Carbon Dating Chemistry Tutorial
Radiometric dating, often called radioactive dating, is a technique used to determine the age of materials such as rocks. It is based on a comparison between the. The methods discussed in this chapter are based on radioactive decay [see. Sect . , Eqs. ( and eudialyte are especially suitable. Between and g. Given that eudialytes are easily altered and commonly contain inclusions of be determined quantitatively by application of radiometric dating methods to.
The sample-context relationship must be established prior to carbon dating. The radiocarbon dating process starts with measuring Carbon, a weakly radioactive isotope of Carbon, followed by calibration of radiocarbon age results to calendar years. History, anthropology, and archaeology are three distinct but closely related bodies of knowledge that tell man of his present by virtue of his past. Historians can tell what cultures thrived in different regions and when they disintegrated.
Archaeologists, on the other hand, provide proof of authenticity of a certain artifact or debunk historical or anthropological findings. Studying the material remains of past human life and activities may not seem important or exciting to the average Joe unlike the biological sciences. It is in knowing what made past cultures cease to exist that could provide the key in making sure that history does not repeat itself.
Over the years, archaeology has uncovered information about past cultures that would have been left unknown had it not been with the help of such technologies as radiocarbon dating, dendrochronologyarchaeomagnetic dating, fluoride dating, luminescence dating, and obsidian hydration analysis, among others. Radiocarbon dating has been around for more than 50 years and has revolutionized archaeology.
Carbon 14 dating remains to be a powerful, dependable and widely applicable technique that is invaluable to archaeologists and other scientists. Radiocarbon Dating Concept The unstable and radioactive carbon 14, called radiocarbon, is a naturally occurring isotope of the element carbon. When a living thing dies, it stops interacting with the biosphere, and the carbon 14 in it remains unaffected by the biosphere but will naturally undergo decay. Decay of carbon 14 takes thousands of years, and it is this wonder of nature that forms the basis of radiocarbon dating and made this carbon 14 analysis a powerful tool in revealing the past.
The process of radiocarbon dating starts with the analysis of the carbon 14 left in a sample. Calibration is then done to convert BP years into calendar years. This information is then related to true historical dates. Is Carbon Dating the Right Method? Before deciding on using carbon dating as an analytical method, an archaeologist must first make sure that the results of radiocarbon dating after calibration can provide the needed answers to the archaeological questions asked.
The implication of what is represented by the carbon 14 activity of a sample must be considered. The sample-context relationship is not always straightforward. Date of a sample pre-dates the context it is found.
Some samples, like wood, already ceased interacting with the biosphere and have an apparent age at death and linking them to the age of the deposits around the sample would not be wholly accurate.
There are also cases when the association between the sample and the deposit is not apparent or easily understood. Great care must be exercised when linking an event with the context and the context with the sample to be processed by radiocarbon dating. An archaeologist must also make sure that only the useful series of samples are collected and processed for carbon dating and not every organic material found in the excavation site.
Radiocarbon Scientists—Archaeologists Liaison It is important that the radiocarbon scientists and archaeologists agree on the sampling strategy before starting the excavation so time, effort, and resources will not be wasted and meaningful result will be produced after the carbon dating process.
It must be stressed that archaeologists need to interact with radiocarbon laboratories first before excavation due to several factors.
Radiometric dating - Simple English Wikipedia, the free encyclopedia
Sample type, size and packing Laboratories have limitations in terms of the samples they can process for radiocarbon dating. While the moment in time at which a particular nucleus decays is unpredictable, a collection of atoms of a radioactive nuclide decays exponentially at a rate described by a parameter known as the half-lifeusually given in units of years when discussing dating techniques.
After one half-life has elapsed, one half of the atoms of the nuclide in question will have decayed into a "daughter" nuclide or decay product. In many cases, the daughter nuclide itself is radioactive, resulting in a decay chaineventually ending with the formation of a stable nonradioactive daughter nuclide; each step in such a chain is characterized by a distinct half-life. In these cases, usually the half-life of interest in radiometric dating is the longest one in the chain, which is the rate-limiting factor in the ultimate transformation of the radioactive nuclide into its stable daughter.
Isotopic systems that have been exploited for radiometric dating have half-lives ranging from only about 10 years e. It is not affected by external factors such as temperaturepressurechemical environment, or presence of a magnetic or electric field.
For all other nuclides, the proportion of the original nuclide to its decay products changes in a predictable way as the original nuclide decays over time. This predictability allows the relative abundances of related nuclides to be used as a clock to measure the time from the incorporation of the original nuclides into a material to the present.
Accuracy of radiometric dating[ edit ] Thermal ionization mass spectrometer used in radiometric dating. The basic equation of radiometric dating requires that neither the parent nuclide nor the daughter product can enter or leave the material after its formation. The possible confounding effects of contamination of parent and daughter isotopes have to be considered, as do the effects of any loss or gain of such isotopes since the sample was created.
It is therefore essential to have as much information as possible about the material being dated and to check for possible signs of alteration. Alternatively, if several different minerals can be dated from the same sample and are assumed to be formed by the same event and were in equilibrium with the reservoir when they formed, they should form an isochron. This can reduce the problem of contamination. In uranium—lead datingthe concordia diagram is used which also decreases the problem of nuclide loss.
Finally, correlation between different isotopic dating methods may be required to confirm the age of a sample. For example, the age of the Amitsoq gneisses from western Greenland was determined to be 3. The procedures used to isolate and analyze the parent and daughter nuclides must be precise and accurate.
This normally involves isotope-ratio mass spectrometry. For instance, carbon has a half-life of 5, years. After an organism has been dead for 60, years, so little carbon is left that accurate dating cannot be established. On the other hand, the concentration of carbon falls off so steeply that the age of relatively young remains can be determined precisely to within a few decades. Closure temperature If a material that selectively rejects the daughter nuclide is heated, any daughter nuclides that have been accumulated over time will be lost through diffusionsetting the isotopic "clock" to zero.
The temperature at which this happens is known as the closure temperature or blocking temperature and is specific to a particular material and isotopic system. These temperatures are experimentally determined in the lab by artificially resetting sample minerals using a high-temperature furnace.
Radiocarbon Dating and Archaeology
As the mineral cools, the crystal structure begins to form and diffusion of isotopes is less easy. At a certain temperature, the crystal structure has formed sufficiently to prevent diffusion of isotopes.
This temperature is what is known as closure temperature and represents the temperature below which the mineral is a closed system to isotopes.Debunking Creationism: "Radiometric Dating Is Unreliable!"
Thus an igneous or metamorphic rock or melt, which is slowly cooling, does not begin to exhibit measurable radioactive decay until it cools below the closure temperature. The age that can be calculated by radiometric dating is thus the time at which the rock or mineral cooled to closure temperature. This field is known as thermochronology or thermochronometry.
The age is calculated from the slope of the isochron line and the original composition from the intercept of the isochron with the y-axis. The equation is most conveniently expressed in terms of the measured quantity N t rather than the constant initial value No. The above equation makes use of information on the composition of parent and daughter isotopes at the time the material being tested cooled below its closure temperature. This is well-established for most isotopic systems.
Plotting an isochron is used to solve the age equation graphically and calculate the age of the sample and the original composition. Modern dating methods[ edit ] Radiometric dating has been carried out since when it was invented by Ernest Rutherford as a method by which one might determine the age of the Earth.
In the century since then the techniques have been greatly improved and expanded. The mass spectrometer was invented in the s and began to be used in radiometric dating in the s. It operates by generating a beam of ionized atoms from the sample under test. The ions then travel through a magnetic field, which diverts them into different sampling sensors, known as " Faraday cups ", depending on their mass and level of ionization.
On impact in the cups, the ions set up a very weak current that can be measured to determine the rate of impacts and the relative concentrations of different atoms in the beams. Uranium—lead dating method[ edit ] Main article: Uranium—lead dating A concordia diagram as used in uranium—lead datingwith data from the Pfunze BeltZimbabwe. This scheme has been refined to the point that the error margin in dates of rocks can be as low as less than two million years in two-and-a-half billion years.
Zircon has a very high closure temperature, is resistant to mechanical weathering and is very chemically inert. Zircon also forms multiple crystal layers during metamorphic events, which each may record an isotopic age of the event. This can be seen in the concordia diagram, where the samples plot along an errorchron straight line which intersects the concordia curve at the age of the sample. Samarium—neodymium dating method[ edit ] Main article: Samarium—neodymium dating This involves the alpha decay of Sm to Nd with a half-life of 1.
Accuracy levels of within twenty million years in ages of two-and-a-half billion years are achievable. Potassium—argon dating This involves electron capture or positron decay of potassium to argon Potassium has a half-life of 1. Rubidium—strontium dating method[ edit ] Main article: